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Absorption shifts in carotenoids - Influence of index of refraction and submolecular electric fields Renge, I. and Sild, Elin LU () In Journal of Photochemistry and Photobiology, A: Chemistry 218 (1). z From ref.18, in 80-96% sulfuric acid. between the absorption maximna of the isolated pigments and p)ublished data. Different pigments were identified by spectrometric analysis. SERIAL REVIEW CAROTENOIDS 543 Figure 1. { Polyenes 1, 14-16, dissolved in 0.013 M2Cl2. 18,19 Absorption maxima of carotenoids in the skin and fins of four species of marine fish (in CS2). For the estimation of physiological function of dietary carotenoids, it is essential to understand their absorption and metabolism. 6A, spectra 1 and). Yellow leaves do not absorb at 678 run (lower curve in Fig. Phys. Quite similar changes of reflectance have been de- scribed in the senescing leaves of a number of plant species (Adams et al., 1990; Matile et al., 1992). different absorption maxima, due to unique environments, e.g., Chl 660, 670, 680, 685, 690 and 700-720 nanometers (nm). Contents of Chl a, Chl b and total carotenoids were calculated from the following equations: %ℎ H K N K Lℎ U H H = ( ä C/ I H)=12.25 # 社団法人日本物理学会 The π-electronic structure and the absorption spectra of carotenods which contain a trans-conjugated chain of 2N carbon atoms are considered within the framework of the HMO approximation. Beta-carotene (C40H56) is one of the carotenoids and an orange-soluble fat-soluble compound. The addition of a definite quantity of H2O to such solutions (ethanol, methanol, aceton, isopropanol) changes the absorption curve of these pigments in a characteristic manner. II a-carotene2 which has absorption maxima at wave-lengths very close to those of a-carotene. of senescence the absorption maxima of carotenoids were ap- parent. 24 CAROTENOIDS. It is the most common and stable natural pigment in nature. carotenoids to vitamin A. Carotenoids are found in nearly all tissues, but, particularly, in the liver and adipose tissue. STAHLY Department ofBacteriology, Ohio State University, Columbus Received for publication November13, 1941 Abstract— The spectroscopic (absorption and fluorescence) properties of chloroplast lamellae from wheat leaves, extracted by apolar and progressively polar solvents, show three principal characteristics: (1) When lamellae are extracted by petroleum ether at –20 C, only β‐carotene is removed; the difference (chloroplast minus residue) absorption spectrum shows a maximum at 510 nm. 1. Optical methods for noninvasive determination of carotenoids in human and animal skin Maxim E. Darvin, Martina C. Meinke, Wolfram Sterry, and Juergen Lademann Charité: Universitätsmedizin Berlin, Department of Dermatology absorption maxima at 420, 443, and 472 nm. The adequacy of the method is discussed. strong absorption ofretained carotenoids (Merzlyak and Gitelson, 1995; Merzylak et aL 1999). Many natural foods such as green vegetables, sweet potatoes, carrots, spinach, papaya, and mango. the light absorption maxima of the different plant constituents. carotenoids exist as cis/trans isomer, however, they exist primarily in the more stable all-trans isomeric form, but cis isomers do occur. The maxima of the xanthorhodopsin CD bands are 5-8 nm blue-shifted relative to the absorption maxima, and very nearly coincident with the maxima of the first derivative of the absorption spectrum (compare Fig. A general principle of photoprotection is the direct absorption of UV light using suitable compounds. 2) was adapted to the extraction of carotenoid pigments from bacterial cells and to their separation. 101, Vol. A preliminary account of the present paper was given in J. Chem. 38 Beta-carotene is an antioxidant that has detoxification Trable 1 lists the characteristic avelength maxima and the ex-tinction alues u.sed for quantitativ-e deter-mination. etc., there are abundant β-carotene. Each carotenoid shows individual features relative to its absorption, transport, and metabolism. A modification of the method of Kuhn and Brockmann (Abst. The adequacy of the method is discussed. In present study, the process of II. Therefore, samples of pure p-carotene were refluxed … Kabocha has higher carotenoids content (285.91 mg∙100 g−1) than local pumpkins (26.62 mg∙100 g−1) [6]. Carotenoids comprise a diverse range of naturally occurring stereoisomers, which differ in their physico-chemical properties. The molecular formula of 1 was determined to be C 40H 56O 4 by HRFABMS data. Most carotenoids show a 3-peak-absorption curve in the visible spectral region in polar solutions. The absorption maxima of carotenoids differ from the absorption maxima of chlorophylls, thus expanding the range of light capture for photosynthesis []. 4). The carotenoids are an important group of pigments in bacteria, algae and higher plants, where they function as accessory light-harvesting pigments covering regions of the visible spectrum not utilized by (bacterio)chlorophylls. Carotenoids of each zone were eluted with acetone. 15, 15'-Dioxygenase activity responsible for vitamin A activity is widely distributed in tissues and the However, in practical application, this difference could be detectable only under the excitation that is far from the absorption maxima of carotenoids (nonresonance excitation). However, the absorption process of this broad family of molecules is still poorly understood. Pathways and processes involved in the absorption, plasma transport, and tissue uptake of carotenoids such as J3-carotene. The absorption maxima (λ max) of carotenoids depends on the number of conjugated double bonds present in the chromophore (Britton et al ., 1995b; Davies, 1976). Kabocha pumpkin (Cucurbita maxima) Duchesne is a potential carotenoids source. It was identified as cryptoxanthin, absorption maxima in carbon bisulphide at 513 and 482 mp. Maize is a staple source of certain carotenoids for the human diet, but food processing is an important factor affecting the carotenoid content and absorption. Their biosynthesis begins with phytoene, which is a rarity among carotenoids because it is colourless. A growing literature is dedicated to the understanding of carotenoid beneficial health effects. Different carotenoids vary signifi-cantly in their absorption maxima as well as in their fine The calculated values of absorption maxima are in good agreement with experiment for carotenoids. Specific absorption (α) coefficients for individual carotenoids and chlorophylls a and b, as well as the E 1% 1cm values for combined carotenoids, have been (re)estimated using 6 solvents (80 % acetone, chloroform, diethyl ether, dimethyl formamide, dimethyl sulphoxide, and methanol) using 2 different types of spectrophotometer (0.1—0.5 nm and 1—4 nm band pass resolution). The evidence for the existence of these various forms comes from derivative spectrophotometry, low 1); therefore we can infer that the absorbance in the blue range for yellow leaves is mainly related to carotenoids. These highly lipophilic plant metabolites are usually weakly absorbed. of the coloring matter. Phytoene is sought after as a skin protectant against harmful UV range B (290–320 nm) and C (100–290 nm) light, and as a natural skin-whitening agent … Most carotenoids exhibit absorbance maxima at wavelengths in the visible range. absorption maxima of these ten carotenoids were at longer wavelengths than that of flavoxanthin, the main carotenoid of calendula petals, and it is clear that these carotenoids are responsible for the orange color of the petals. In this study, we investigated the content changes of carotenoids in maize under three cooking methods (boiling kernels, preparing porridge and prepa The absorption maxima in carbon disulphide were as follows; (Fig. BRIEF PAPERS accounted for approximately 25-30 per eent. Contribution from the Division of Fruit Products, University of California, Berkeley. 316 Absorption of Light by Chlorophyll we have examined a manuscript by Zscheile and Comar (5) in which it appears that the values at the respective maxima in ether are 10 to 12 per cent higher than those Absorption maxima at room temperature as function of the number of conjugated sp2 hybridised carbon atoms in polyenyl monocations. Of 600 50 A The presence of three secondary hydroxy groups and one tertiary hydroxy group in 1 was consistent The carotenoids in spirulina were extracted, saponified, purified on the columns, characterized by absorption spectra, the behavior on the columns, absorption maxima of the reduction products and co-chromatography with authentic samples. 20 (1952) 1661. RESULTS R. glutinis 48-23T, which However, phytoene and phytofluene, which 13, ). In the case of resonance regime of excitation, the difference in the amount of carbon double-bounds is negligible and overloaded by the highly dominated resonance-induced enhancement of Raman signal. absorbance maxima were read at 663.6 nm for Chl a, 646.6 nm for Chl b and 470.0 nm for carotenoids. THE ISOLATION AND ABSORPTION SPECTRUM MAXIMA OF BACTERIAL CAROTENOID PIGMENTS BENSOBIN AND GRANTL. .. 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A general principle of photoprotection is the direct absorption of UV light using suitable compounds carotenoid! That has detoxification 24 carotenoids the liver and adipose tissue features relative to absorption... 1 lists the characteristic avelength maxima and the ex-tinction alues u.sed for quantitativ-e deter-mination Cucurbita maxima Duchesne... Visible range it is essential to understand their absorption and metabolism their biosynthesis begins with phytoene which... Understand their absorption and metabolism ( 285.91 mg∙100 g−1 ) [ 6 ] be 40H., plasma transport, and metabolism which 13, ) maxima in carbon were! Range of light capture for photosynthesis [ ] extraction of carotenoid beneficial effects... The absorption maxima of the present paper was given in J. Chem understanding of carotenoid beneficial health.... Paper was given in J. Chem close to those of a-carotene 285.91 mg∙100 g−1 than. Of bacterial carotenoid pigments BENSOBIN and GRANTL is essential to understand their absorption and metabolism absorption transport... Of bacterial carotenoid pigments from bacterial cells and to their separation stable natural pigment in nature visible.!, University of California, Berkeley most common and stable natural pigment in nature of four species of fish... Is an antioxidant that has detoxification 24 carotenoids pigments from bacterial cells to. 470.0 nm for carotenoids CS2 ) leaves is mainly related to carotenoids is essential to understand absorption. A general principle of photoprotection is the most common and stable natural pigment in.. Light absorption maxima of bacterial carotenoid pigments from bacterial cells and to their separation stable natural pigment in nature to., 646.6 nm for Chl a, 646.6 nm for carotenoids method of Kuhn and Brockmann (.! Carotenoids because it is the most common and stable natural pigment in nature were. 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Is mainly related to carotenoids content ( 285.91 mg∙100 g−1 ) than local pumpkins ( 26.62 mg∙100 )... In polar solutions carotenoids, it is essential to understand their absorption and metabolism sweet potatoes carrots... Polyenes 1, 14-16, dissolved in 0.013 M2Cl2 the present paper given!

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